21CrMoV5-7 Chemical Composition (EN 10269 / Werkstoff 1.7709)

The chemistry of 21CrMoV5-7 (Werkstoff 1.7709) is fixed by EN 10269 within a tight Cr-Mo-V Q+T window. The chemistry is the controlling input for the secondary-hardening behaviour during the temper at 680 to 740 deg C and the resulting creep-rupture performance at 500 to 550 deg C metal temperature. Each element is bounded for a specific metallurgical purpose.

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Element Ranges (EN 10269)

ElementMin %Max %Metallurgical role
Carbon (C)0.170.25Q+T hardenability backbone; supports V4C3 secondary hardening
Silicon (Si)0.40Deoxidation residual; slight solid-solution strengthening
Manganese (Mn)0.400.80Hardenability through CCT shift; solid-solution strengthening
Phosphorus (P)0.030Tramp limit for impact toughness and transverse ductility
Sulphur (S)0.030Tramp limit; modified MnS shape control via Ca treatment optional
Chromium (Cr)1.201.50Through-thickness hardenability and creep resistance
Molybdenum (Mo)0.550.80Secondary hardening with V; temper-embrittlement resistance
Vanadium (V)0.200.35Drives V4C3 precipitation at 680 to 740 deg C temper
Nickel (Ni)0.60Residual; toughness contribution at low temperature
Aluminium (Al)0.030Grain refinement via AlN precipitation; deoxidation
Copper (Cu)0.30Residual limit
Iron (Fe)balanceMatrix

PMI Verification

Positive material identification by handheld XRF or OES is supplied on call-out per stud or per heat-lot batch. PMI report includes Cr, Mo, V, Mn, Ni, Cu and Fe with tolerance pass/fail against the EN 10269 21CrMoV5-7 window. Carbon, sulphur and phosphorus are reported from the mill chemistry on the EN 10204 type 3.1 or 3.2 certificate (XRF cannot quantify light elements).

Chemistry vs Neighbouring Grades

Element21CrMoV5-721CrMoV5-11ASTM A193 B16Durehete 1055 (1.7729)
C0.17 to 0.250.17 to 0.250.36 to 0.470.17 to 0.24
Cr1.20 to 1.501.20 to 1.500.80 to 1.150.80 to 1.20
Mo0.55 to 0.800.90 to 1.100.50 to 0.650.55 to 0.75
V0.20 to 0.350.25 to 0.350.25 to 0.350.20 to 0.40
Ti0.04 to 0.10
B0.0010 to 0.0050

Heat-Lot Traceability

Every 21CrMoV5-7 stock item ships with a heat number that ties back to the melt-shop pour record. The EN 10204 type 3.1 certificate carries the full chemistry, ladle position, deoxidation practice, and any PMI confirmation. For type 3.2 certification, a third-party witness (Lloyd's Register, DNV, BV, SGS, TUV) verifies the heat-lot identity match between bar stock, machined fastener and shipped certificate.

Frequently Asked Questions

Q. What is the carbon content of 21CrMoV5-7?
0.17 to 0.25 percent. The carbon range is set low enough to allow good through-thickness hardenability in the Q+T cycle while keeping carbide coarsening under control during the secondary-hardening temper.

Q. Why is vanadium critical in 21CrMoV5-7?
Vanadium (0.20 to 0.35 percent) drives the secondary-hardening peak through V4C3 carbide precipitation during tempering. The fine V4C3 dispersion is what gives the grade its long-time creep-rupture performance.

Q. What is the role of chromium in the chemistry?
Chromium (1.20 to 1.50 percent) provides through-thickness hardenability and stabilises the carbide network for creep resistance.

Q. Are the sulphur and phosphorus limits tighter than ASTM A193 B16?
Yes. EN 10269 caps S and P at 0.030 percent for 21CrMoV5-7. B16 caps S at 0.040 percent and P at 0.035 percent. Tighter limits reflect the higher impact-toughness target.

Drill into 21CrMoV5-7 properties: Mechanical Properties · Heat Treatment (Q+T Cycle) · Elevated-Temperature Properties · Hardness · Creep-Rupture · Welding Procedure · Machinability. Standards: EN 10269 · vs ASTM A193 B16. Back to the 21CrMoV5-7 Alloy Hub.